Two complexes of copper(II) salts with 5-amino-3-(pyrid-2-yl)-1H-pyrazole, the prototype for a new class of ditopic ligand.
نویسندگان
چکیده
The title ligand ('L') in crystalline [CuBrL(2)]Br.CH(3)OH and [Cu(OH(2))L(2)]SO(4).H(2)O.CH(3)OH chelates to both the copper(II) cations and the charge-balancing anions.
منابع مشابه
Synthesis, structural, magnetic, DFT calculations and CShM studies of three new pentanuclear Mn(II) clusters.
The ditopic ligand PyPzOAPz (N-[(Z)-amino(pyrazin-2-yl)methylidene]-5-methyl-1-(pyridin-2-yl)-1H-pyrazole-3-carbohydrazonic acid) was synthesized by in situ condensation of methyl imino pyrazine-2-carboxylate with 5-methyl-1-(2-pyridyl) pyrazole-3-carbohydrazide. In this work we have also used two of our earlier ligands PzCAP (5-methyl-N-[(1E)-1-(pyridin-2-yl)ethylidene]-1H-pyrazole-3-carbohydr...
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عنوان ژورنال:
- Dalton transactions
دوره 5 شماره
صفحات -
تاریخ انتشار 2006